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Multifunctional xGnP/LLDPE Nanocomposites Prepared by Solution Compounding Using Various Screw Rotating Systems
Authors:Sumin Kim  Inhwan Do  Lawrence T. Drzal
Affiliation:1. Department of Architecture, College of Engineering Soongsil University, Seoul 156‐743, Republic of Korea;2. Composite Materials and Structures Center, College of Engineering, Michigan State University, 2100 Engineering Building East Lansing, MI 48824‐1226, USA
Abstract:xGnP‐Reinforced LLDPE nanocomposites have been prepared using co‐, counter‐ and modified corotating screw systems. The highest tensile strength and modulus were shown in the case of composites made by counter‐rotating screws. The percolation threshold of exfoliated graphite nanoplatelet/LLDPE nanocomposites was between 12 and 15 wt.‐%. The change of crystallinity caused by exfoliated graphite nanoplatelet loading was monitored using DSC and XRD. It was found that solution mixing showed better dispersion of exfoliated graphite nanoplatelets than melt mixing, and counter‐rotating screws produced better dispersion of the exfoliated graphite nanoplatelets than co‐ and modified corotating screws even though bubbling appeared during mixing in the barrel.
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Keywords:exfoliated graphite nanoplatelets (xGnP)  LLDPE  nanocomposites  resistivity
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