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A simple transient model for a high temperature PEM fuel cell impedance
Authors:O. Shamardina  M.S. Kondratenko  A.V. Chertovich  A.A. Kulikovsky
Affiliation:1. Lomonosov Moscow State University, Faculty of Physics, 119991 Moscow, Russia;2. Institute for Energy Research – Electrochemical Process Engineering (IEK-3), Research Centre “Jülich”, D-52425 Jülich, Germany
Abstract:We develop a pseudo two-dimensional, isothermal transient model for a high temperature proton exchange membrane fuel cell. It takes into account the dynamic change of oxygen concentration in the cathode gas diffusion layer and in the cathode channel. The model can be used to simulate and analyze electrochemical impedance spectra of the cell in both potentiostatic and galvanostatic modes, current interrupt results and step changes in the cell current or potential. The model is validated by fitting experimental data.
Keywords:HT-PEMFC   Modeling   Transient behavior   Impedance
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