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Efficient multi-metallic anode catalysts in a PEM water electrolyzer
Authors:KB Kokoh  E Mayousse  TW Napporn  K Servat  N Guillet  E Soyez  A Grosjean  A Rakotondrainibé  J Paul-Joseph
Affiliation:1. IC2MP UMR CNRS 7285, “Equipe SAMCat”, Université de Poitiers, 4 rue Michel Brunet B27, BP 633, 86022 Poitiers cedex, France;2. CEA, LITEN, DEHT/LCPEM, 17 rue des Martyrs, F-38054 Grenoble, France;3. HELION Hydrogen Power, Domaine du Petit Arbois, Bâtiment Jules Verne, BP 71, 13545 Aix en Provence, France
Abstract:Anode catalysts synthesized by the thermal decomposition method were used for splitting water in PEM electrolysis cells. Although the area resistance of the ternary anode materials increased, the Ti content in the ruthenium and iridium based catalysts have led to an energy consumption of 4.5 kWh/Nm3(H2) at 60 °C. The Membrane Electrode Assemblies have given information on the strong dependence of the membrane thickness. The crossover of hydrogen through Nafion®117 is two-fold lower than that measured in the presence of Nafion®115. Life testing was attempted with supplying the electrolyzer by solar power source. Importantly, the proton exchange membrane water electrolyzer (PEMWE) cell has involved a constant cell voltage at 1 A cm−2 over 800 h durability tests.
Keywords:Renewable energy  PEM water electrolyzer  H2 permeation  Durability  Cell voltage  Anode materials
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