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The voidage problem in gas-electrolyte dispersions
Authors:H Vogt
Affiliation:(1) Fachbereich Verfahrens- und Umwelttechnik, Technische Fachhochschule Berlin, D-1000 Berlin 65, Germany
Abstract:Assessing the ohmic interelectrode resistance of electrochemical reactors with gas evolution requires data for the gas void fraction of gas-electrolyte dispersions. A voidage equation is derived taking account of the internal liquid flow in stationary electrolytes and at small liquid superficial velocities. The equation is a general form of available voidage equations.Nomenclature C non-dimensional constant, Equation 8 - n exponent, Equation 5 - S cross-sectional area (m2) - v G gas velocity (m s–1) - v L liquid velocity (m s–1) - v s rising velocity of a bubble swarm (m s–1) - v l terminal rising velocity of a single bubble (m s–1) - VG volume flow rate of gas (m3 s–1) - VL volume flow rate of liquid (m3 s–1) - agr fraction of cross-sectional area - epsi volume (void) fraction of gas - epsim geometric maximum of void fraction - epsiinfin maximum of void fraction in infinite gas flow Indices i internal - t total
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