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聚苯胺纳米纤维的合成及表征
引用本文:赵海沨,韩冰,赵辉. 聚苯胺纳米纤维的合成及表征[J]. 广州化工, 2014, 0(18): 60-62
作者姓名:赵海沨  韩冰  赵辉
作者单位:开封大学功能材料研究中心,河南 开封,475004
基金项目:河南省科技厅基础与前沿技术研究计划项目(No112300410039)。
摘    要:以D-樟脑磺酸为掺杂剂,十二烷基苯磺酸钠为软模板,过硫酸铵为氧化剂,在水溶液体系中通过苯胺原位聚合制备得到聚苯胺纳米纤维,对其进行了紫外和红外的表征,并使用SEM对其形貌进行了观测。进一步研究结果表明,樟脑磺酸的掺杂可促进聚苯胺纳米纤维的形成,并同时起到掺杂剂和软模板的双重作用;通过控制反应的时间,可调节产物的形貌结构。

关 键 词:聚苯胺纳米纤维  樟脑磺酸  十二烷基苯磺酸钠

Synthesis and Characterization of Polyaniline Nanofibers
ZHAO Hai-feng,HAN Bing,ZHAO Hui. Synthesis and Characterization of Polyaniline Nanofibers[J]. GuangZhou Chemical Industry and Technology, 2014, 0(18): 60-62
Authors:ZHAO Hai-feng  HAN Bing  ZHAO Hui
Affiliation:ZHAO Hai-feng;HAN Bing;ZHAO Hui;Research Center of Functional Materials,Kaifeng University;
Abstract:With D-camphor sulfonic acid as a dopant , sodium dodecyl benzene sulfate as soft template , ammonium persulfate as the oxidant in the aqueous system , PANI nanofiber was prepared in situ polymerization of aniline and were characterized by UV, IR and SEM.Further research results showed that camphorsulfonic acid doped polyaniline nanofibers can promote the formation of PANI nanofiber , and also played the dual role of a dopant and a soft template .By controlling the reaction time , the product can be adjusted morphologies .
Keywords:polyaniline nanofibers  camphor sulfonic acid  sodium dodecyl benzene sulfate
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