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非水MDEA混合溶剂对H_2S的选择性脱除
引用本文:徐宏建,张慧鑫,孙雅萍.非水MDEA混合溶剂对H_2S的选择性脱除[J].上海电力学院学报,2010,26(3):242-246.
作者姓名:徐宏建  张慧鑫  孙雅萍
作者单位:上海电力学院,能源与环境工程学院,上海,200090
基金项目:上海高校选拔培养优秀青年教师科研专项基金,上海市教委发展基金 
摘    要:以小型绝热填料吸收和再生塔组合成实验室模拟脱硫装置,综合评价了添加部分有机溶剂时脱硫剂对脱硫效率及选择性因子的影响.以30%(wt)MDEA水溶液为基准,实验筛选了N—甲基吡咯烷酮(NMP)、乙二醇(EG)等9种有机添加溶剂.综合评价可得,以添加合适的有机溶剂替代大部分水而组成的MDEA非水溶剂具有比MDEA水溶液更高的脱硫选择性,但其脱硫效率略低.

关 键 词:绝热填料塔  硫化氢  MDEA混合溶剂  选择性脱硫
收稿时间:2009/6/30 0:00:00

Removal of H2S and Evaluation of Non-aqueous MDEA Mixed Solutions
XU Hong-jian,ZHANG Hui-xin and SUN Ya-ping.Removal of H2S and Evaluation of Non-aqueous MDEA Mixed Solutions[J].Journal of Shanghai University of Electric Power,2010,26(3):242-246.
Authors:XU Hong-jian  ZHANG Hui-xin and SUN Ya-ping
Affiliation:XU Hong-jian,ZHANG Hui-xin,SUN Ya-ping(School of Thermal Power and Enviromental Engineering,Shanghai University of Electric Power,Shanghai 200090,China)
Abstract:An experimental apparatus composed of adiabatic packed absorption and regeneration columns is established to simulate H2S removal process.By this apparatus,nine non-aqueous Methyldiethanolamine(MDEA) solutions are evaluated under the fixed operation conditions.The results indicate that the selectivity of H2S removal increases evidently with N-Methylprrolidone and Ethylene glycol as non-aqueous solvents respectively but the efficiency of desulphurization is somewhat lower compared with 30%(wt) aqueous MDEA s...
Keywords:adiabatic packed column  H2S  MDEA mixed solution  selective desulphurization  
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