Design criteria for the crystallization of an organic salt from an aqueous solution

Results from laboratory experiments and a 500 tonnes per month pilot plant have been used to draw up criteria for designing the crystallization of an organic salt from its aqueous solution. The crystallization kinetics were determined in a continuous forced circulation crystallizer. The experiments in the forced circulation evaporative crystallizer were carried out and evaluated in accordance with the MSMPR (mixed suspension mixed product removal) concept.The residence time was varied between 0.8 and 10 hours, and the density of the suspension between 180 and 870 kg m^?3. It was found that, within the residence time and suspension density ranges studied, growth and nucleation rates have the same dependence on the supersaturation. On the other hand, the nucleation rate decreases with increasing suspension density. If the crystallization kinetics and other design criteria, such as vapour velocity, i.e. supersaturation ratio in the vicinity of the evaporative surface, or height of liquid above the heat exchangers, are taken into account, it is possible to obtain a space—time yield which is five times higher than in the pilot plant, so that the plant to be built can be designed to be correspondingly smaller.