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强化混凝技术处理南淝河污染水的效果
引用本文:陈义飞,孙琴,丁士明,姚羽,陈开宁,孙庆业. 强化混凝技术处理南淝河污染水的效果[J]. 水资源保护, 2015, 31(4): 103-110
作者姓名:陈义飞  孙琴  丁士明  姚羽  陈开宁  孙庆业
作者单位:上海市政工程设计研究总院第六设计院, 安徽 合肥 230001,河海大学浅水湖泊综合治理与资源开发教育部重点实验室, 江苏 南京 210098; 河海大学环境学院, 江苏 南京 210098,河海大学环境学院, 江苏 南京 210098,河海大学浅水湖泊综合治理与资源开发教育部重点实验室, 江苏 南京 210098,中国科学院南京地理与湖泊所湖泊与环境国家重点实验室, 江苏 南京 210008,安徽大学资源与环境工程学院, 安徽 合肥 230039
基金项目:国家水体污染控制与治理科技重大专项(2012ZX07103-002)
摘    要:选用聚合氯化铁(PFC)、聚合硫酸铁(PFS)、聚合氯化铝(PAC)和聚合氯化铝铁(PAFC)作为混凝剂;选用阳离子型聚丙烯酰胺(CPAM)、阴离子型聚丙烯酰胺(APAM)和非离子型聚丙烯酰胺(NPAM)作为助凝剂,通过室内试验对比研究强化混凝技术中多种混凝剂单用及其和助凝剂联用对南淝河污染水的除浊和去污效果,并用于南淝河现场构建的混凝沉淀系统。结果表明,4种混凝剂单用时,PAFC对浊度、TP去除效果最优,对CODMn有良好的去除效果,且不影响原水的p H值,而PFC和PFS单用时可明显降低原水p H值,4种混凝剂单用时对TN均没有明显去除效果;PAFC与CPAM联用时对浊度的去除效果最佳,明显优于PAFC与APAM和NPAM联用和PAFC单用的效果;混凝剂与CPAM联用提高了其除浊和去除TP的能力,但不能明显改善其去除CODMn的效果,对原水p H和TN的影响与单用时相同。选取"PAFC+CPAM"作为南淝河示范工程的混凝剂和助凝剂,现场混凝沉淀出水水质稳定,浊度和TP的去除效果较好,去除率分别达到90%和80%,对CODMn的去除率约为52%,而对TN的去除效果有限,去除率约为22.4%。

关 键 词:强化混凝技术;混凝剂;助凝剂;污染水
收稿时间:2014-03-11

Effect of enhanced coagulation technology for treatment of polluted water from Nanfei River
CHEN Yifei,SUN Qin,DING Shiming,YAO Yu,CHEN Kaining and SUN Qingye. Effect of enhanced coagulation technology for treatment of polluted water from Nanfei River[J]. Water Resources Protection, 2015, 31(4): 103-110
Authors:CHEN Yifei  SUN Qin  DING Shiming  YAO Yu  CHEN Kaining  SUN Qingye
Affiliation:The Sixth Design Institute of Shanghai Municipal Engineering Design Institute, Hefei 230001, China,Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, Hohai University, Nanjing 210098, China; School of Environment, Hohai University, Nanjing 210098, China,School of Environment, Hohai University, Nanjing 210098, China,Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, Hohai University, Nanjing 210098, China,State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008, China and School of Resources and Environmental Engineering, Anhui University, Hefei 230039, China
Abstract:A series of indoor experiments were conducted to investigate the effects of different coagulants used single or combined with coagulant aids on removal of turbidity and decontamination of polluted water from Nanfei River, which will be further applied in coagulation and precipitation system of on-site construction for this river. Polymeric ferric chloride(PFC), polymeric ferric sulfate(PFS), polyaluminum chloride(PAC)and polyaluminum ferric chloride(PAFC)were selected as coagulants, and cationic polyacrylamide(CPAM), anionic polyacrylamide(APAM)and non-ionic polyacrylamide(NPAM)as coagulant aids. The results showed that four coagulants used only PAFC had high removal effect on turbidity, TP and CODMn, and did not affected the pH value of raw water, while the PFC and PFS which were used alone obviously reduced the pH value of raw water, Four coagulants which were used alone had little effect on removal of TN in water; The combined use of PAFC and CPAM has the best effect on turbidity, comparing to the effect of single use of PAFC, and their combined use with APAM; The combined uses of coagulants and CPAM enhanced the removal effect of turbidity and TP, but had few effects on the removal of CODMn, and their effects on the pH value of raw water and TN values were similar to their single use. PAFC+CPAM was selected as coagulant and coagulant aid for demonstrative project site of Nanfei River. their combined use achieved a stable treatment, and the turbidity and TP removal effect is good, the removal effect of turbidity and TP was 90% and 80% respectively; the removal rate of CODMn was about 52%; while the removal effect of TN was limited, the removal rate was only about 22. 4%.
Keywords:enhanced coagulation technology(ETC)   coagulant   coagulant aid   polluted water
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