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Effect of growth temperature on diode parameters of n-ZnO/p-Si heterojuction diodes grown by atomic layer deposition
Affiliation:1. Physics Department, College of Education/Shaqlawa, Salahaddin University-Erbil, Iraq;2. Shaqlawa Technical college, Erbil Polytechnic University, Erbil, Iraq;3. Department of Basic Sciences, Faculty of Sciences, Erzurum Technical University, Erzurum, Turkey;4. Radiology Department, Erbil Medical Technical Institute, Erbil Polytechnic University, Erbil, Iraq;5. Department of Physics, Faculty of Science, Firat University, Elazıg, Turkey;6. Nanoscience and Nanotechnology Laboratory, Firat University, Elazig, Turkey;1. Department of Mechatronics Engineering, National Changhua University of Education, Changhua, Taiwan;2. Green Energy & Environment Research Laboratories, Industrial Technology Research Institute, Hsinchu, Taiwan;1. Hasselt University, Institute for Materials Research and IMEC vzw, Division IMOMEC, Inorganic and Physical Chemistry, Diepenbeek, Belgium;2. Vilnius University, Faculty of Physics, Vilnius, Lithuania;1. Key Laboratory of Optical Field Manipulation of Zhejiang Province, and Key Laboratory of ATMMT Ministry of Education, Department of Physics, Zhejiang Sci-Tech University, Hangzhou 310018, PR China;2. Hangzhou Zhongneng Photoelectricity Technology Co., Ltd., Hangzhou 310018, PR China
Abstract:n-ZnO/p-Si heterojunctions were grown by atomic layer deposition (ALD) on (100) p-Si substrates at different growth temperatures in the range of ~100–250 °C. The current-voltage characterization of all the heterojunctions showed typical rectifying behavior, a true signature of a p-n junction diode. The diode grown at 100 °C were having significantly lower reverse saturation current (~21 nA) and high rectification factor (~120) compared to those grown at relatively higher temperatures such as 200 or 250 °C. From capacitance-voltage measurements, it was found that the depletion width in the ZnO side of n-ZnO/p-Si diode was maximum (~60 nm) for the diode grown at 100 °C and decreased gradually to ~3 nm for the diodes grown at high temperatures of 250 °C. The electron concentration in ZnO films was found to increase significantly on increasing the growth temperature from ~100 to 250 °C. The junction capacitance also showed an increasing trend with increase in the growth temperature. The variation of diode parameters with growth temperature has been discussed in terms of carrier concentration in ZnO films and associated growth mechanisms of the ALD. Such low temperature grown n-ZnO/p-Si diodes with lower reverse saturation current and large depletion width may be suitable for photo detection applications.
Keywords:Atomic layer deposition  ZnO thin film  Heterojuction  Diode parameters
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