Influence of MEOBiPA content on the properties of novel photoluminescent thermosensitive hydrogels |
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Authors: | Wen‐Fu Lee Pei‐Ying Liu |
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Affiliation: | Department of Chemical Engineering, Tatung University, Taipei City 104, Taiwan |
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Abstract: | In order to establish a dual functional hydrogel, a special monomer, methacryloyloxy‐ethylene‐oxy‐carbonyl bis4‐(phenyl‐isopropyl)phenyl]amine (MEOBiPA), was prepared from bis4‐(phenyl‐isopropyl)phenyl]‐4‐cyanophenyl amine and 2‐hydroxyethyl methacrylate. Subsequently, a series of thermosensitive hydrogels was obtained through copolymerization of N‐isopropyl acrylamide (NIPAAm) with MEOBiPA by UV irradiation (named the NM series). The effect of MEOBiPA content on the swelling behavior, mechanical properties and drug release behavior of the hydrogels was further investigated. Results showed that the swelling ratios of the NM copolymeric hydrogels decreased from 4.73 to 1.74 g g?1 when the MEOBiPA content in the hydrogel increased from 0.1 to 0.9 mol%. Both gel strength and crosslinking density of the NM hydrogels increased with increasing MEOBiPA. Conversely, the thermosensitive behavior of NM hydrogels significantly decreased upon increase of MEOBiPA content. Likewise, the caffeine release ratio also decreased from 70% to 25%. Notably, the intensity of photoluminescence increased with increasing MEOBiPA content in the hydrogels. Further, the corresponding copolymers of the hydrogels were prepared using free radical polymerization. The UV absorbance and photoluminescent behavior of the MEOBiPA, NIPAAm/MEOBiPA copolymeric hydrogels and their corresponding copolymers in different polar solvents were also investigated. © 2015 Society of Chemical Industry |
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Keywords: | smart materials hydrogels thermosensitive triphenylamine derivatives photoluminescence |
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