| 不饱和聚酯树脂固化动力学研究进展 |
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| 引用本文： | 吴海艳,周莉,臧树良. 不饱和聚酯树脂固化动力学研究进展[J]. 热固性树脂, 2011, 0(3): 50-53 |
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| 作者姓名： | 吴海艳 周莉 臧树良 |
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| 作者单位： | 辽宁石油化工大学化学与材料学院; |
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| 摘 要： | 介绍了不饱和聚酯树脂(UPR)固化反应动力学的n级反应模型和自催化模型,指前因子(A)和表观活化能(E)的求解方法:Kissinger法,Ozawa法和Friedman法以及由Crane方程或形状指数Si求解反应级数(n)的方法,综述了目前国内外DSC法研究UPR固化动力学的进展。
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| 关 键 词： | 不饱和聚酯树脂 示差扫描量热分析 动力学模型 动力学参数 |
Research advances in unsaturated polyester resin curing kinetics |
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| WU Hai-yan,ZHOU Li,ZANG Shu-liang(School of Materials , Chemistry,Liaoning University of Petroleum , Chemical Technology,Fushun ,China. Research advances in unsaturated polyester resin curing kinetics[J]. Thermosetting Resin, 2011, 0(3): 50-53 |
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| Authors: | WU Hai-yan ZHOU Li ZANG Shu-liang(School of Materials & Chemistry Liaoning University of Petroleum Chemical Technology Fushun China |
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| Affiliation: | WU Hai-yan,ZHOU Li,ZANG Shu-liang(School of Materials & Chemistry,Liaoning University of Petroleum and Chemical Technology,Fushun 113001,China |
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| Abstract: | The nth order reaction model and autocatalytic model of unsaturated polyester resin(UPR curing kinetics,calculation methods of preexponential factor(A and activation energy(Eincluding Kissinger,Ozawa and Friedman methods and the solving methods of reaction order by Crane equation or shape index Si were introduced.The recent reseach progresses in curing kinetics of UPR were reviewed. |
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| Keywords: | unsaturated polyester resin(UPR DSC kinetics model kinetics parameter |
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