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GC/MS测定VGO馏分烃类组成及沸点分布研究
引用本文:李诚炜,刘泽龙,田松柏.GC/MS测定VGO馏分烃类组成及沸点分布研究[J].石油炼制与化工,2008,39(10):58-63.
作者姓名:李诚炜  刘泽龙  田松柏
作者单位:石油化工科学研究院 中国石化集团石油化工科学研究院 中国石化基团石油化工科学研究院
基金项目:国家重点基础研究发展计划(973计划) 
摘    要:建立了GC/MS测定VGO馏分烃类组成沸点分布的新方法。该方法采用固相萃取技术分离出饱和烃和芳烃馏分,然后用双柱分流的方式,同时进入质谱和FID检测器,得到样品的色谱图和总离子流色谱图。通过自行编制的数据处理程序,得到VGO样品烃类组成沸点分布,所得结果与标准方法测定结果接近,该方法具有很好的准确性。

关 键 词:色质联用  减压瓦斯油  烃类  组成  沸点  分布  
收稿时间:2008-4-17

STUDY ON THE BOILING POINT DISTRIBUTIONS OF VARIOUS HYDROCARBON TYPES IN VGO BY GC/MS ANALYSIS
Li Chengwei,Liu Zelong,Tian Songbai.STUDY ON THE BOILING POINT DISTRIBUTIONS OF VARIOUS HYDROCARBON TYPES IN VGO BY GC/MS ANALYSIS[J].Petroleum Processing and Petrochemicals,2008,39(10):58-63.
Authors:Li Chengwei  Liu Zelong  Tian Songbai
Abstract:A new method was established for the determination of boiling point distributions of various hydrocarbon types in vacuum gas oil (VGO). The VGO sample was separated into saturates and aromatics by solid-phase extraction, and then the separated samples were divided into MSD and FID for measurement simultaneously using GC/MS unit with a double-column device. The boiling point distributions of various hydrocarbons in VGO were calculated from the FID and TIC chromatograms by a home-developed data processing program. The obtained results agreed well with the test results of standard method.
Keywords:GC/MS  vacuum gas oil  hydrocarbon  composition  boiling point  distribution
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