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掺杂Co对K2Nb4O11光催化性能的影响
引用本文:张浩,张高科,贺方升,邹曦,龚洁. 掺杂Co对K2Nb4O11光催化性能的影响[J]. 武汉理工大学学报, 2007, 29(2): 12-15
作者姓名:张浩  张高科  贺方升  邹曦  龚洁
作者单位:武汉理工大学资源与环境工程学院,武汉,430070
摘    要:采用高温固相法合成了不同Co掺量的K2Nb4O11,通过XRD分析了所合成化合物的物相组成。光催化降解酸性红G的实验结果表明,Co掺量对K2NbO11光催化性能有较大的影响,确定了Co的最佳掺量;K2Nb4O11和CoNb2O6等氧化物的复合效应可能对光催化性能的改善起主要作用;掺Co的K2Nb4O11光催化降解酸性红G的反应动力学符合一级反应。

关 键 词:掺杂  铌酸盐  光催化  酸性红G
文章编号:1671-4431(2007)02-0012-04
修稿时间:2006-09-07

Influence of Co-doped on the Photocatalytic Activity of K2Nb4O11
ZHANG Hao,ZHANG Gao-ke,HE Fang-sheng,ZOU Xi,GONG Jie. Influence of Co-doped on the Photocatalytic Activity of K2Nb4O11[J]. Journal of Wuhan University of Technology, 2007, 29(2): 12-15
Authors:ZHANG Hao  ZHANG Gao-ke  HE Fang-sheng  ZOU Xi  GONG Jie
Abstract:Co-doped K2Nb4O11 powders were obtained by solid-phase reaction method.The structure of the obtained powders was investigated by X-ray diffraction.The photocatalytic degradation of acid red G on the catalyst showed that the contents of cobalt in the catalyst had important effect on the photocatalytic activity of the catalyst.The composite effect of K2Nb4O11 and CoNb2O6 etc may play a major role on improving the photocatalytic activity of the obtained catalyst. The photocatalytic reaction followed with the first order kinetics equation.
Keywords:doped  niobate  photocatalysis  acid red G
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