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| 硅铝杂化P(MMA-BA)耐磨涂料的制备工艺研究 | |
| 引用本文： | 郭斌,银鹏,高勇,郭福全,徐杰,蔡健健,郑勇. 硅铝杂化P(MMA-BA)耐磨涂料的制备工艺研究[J]. 现代涂料与涂装, 2010, 13(4): 7-9 |
| 作者姓名： | 郭斌 银鹏 高勇 郭福全 徐杰 蔡健健 郑勇 |
| 作者单位： | 1. 南京林业大学理学院化学与材料系,南京,210037 2. 福建师范大学化学与材料学院,福州,350007 3. 洛阳理工学院材料科学与工程系,河南,洛阳,471023 |
| 基金项目： | 江苏省"青蓝工程"优秀青年骨干教师项目，江苏省高校自然科学研究计划，南京大学固体微结构物理国家重点实验室开放课题 |
| 摘 要： | 以甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)和乙烯基三乙氧基硅烷(ETES)进行自由基共聚制备预聚物,通过溶胶-凝胶法与铝溶胶制备出了有机-无机杂化耐磨涂料。通过磨耗试验与红外光谱对其制备工艺进行了系统研究,结果表明,当MMA和BA质量比为55∶40,树脂与铝溶胶质量比为10∶1,水解缩聚时间为1 h时,涂膜中有效形成了Si—O—Si和Al—O—Si键,具有较好的透明性和抗紫外能力,其耐磨性最佳。 |
| 关 键 词： | 耐磨性 杂化材料 溶胶-凝胶法 |
Study on Preparation Technology of Aluminum and Silicon Hybrid P(MMA-BA) Wear-resistant Paint |
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| GUO Bin,YIN Peng,GA Yong,GUO Fu-quan,XU Jie,CAI Jian-jian,ZHENG Yong. Study on Preparation Technology of Aluminum and Silicon Hybrid P(MMA-BA) Wear-resistant Paint[J]. Modern Paint and Finishing, 2010, 13(4): 7-9 | |
| Authors: | GUO Bin YIN Peng GA Yong GUO Fu-quan XU Jie CAI Jian-jian ZHENG Yong |
| Affiliation: | GUO Bin, YIN Peng, GAO Yong, GUO Fu-quan, XU Jie, CAI Jian-jian, ZHENG Yong |
| Abstract: | The prepolymer was synthesized by methyl methacrylate, butyl acrylate and triethoxyvinylsilane, and then inorganic-organic hybrid coating was prepared by sol-gel method from the prepolymer and the alumina sol. The preparation technology was systematic studied by wear-test and FT-IR. Results showed that silicon-oxygen-silicon bond and alumina-oxygen-silicon bond were formed, the coating has good transparency and uvioresistant ability, when the ratio of MMA and BA is 55 ： 40, the ratio of prepolymer and alumina sol is 10 ： 1, and hybridization time is 1 hour, wear resistance is the best. |
| Keywords: | wear resistant hybrid material sol-gel |
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