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新型咪唑啉缓蚀剂的合成及其缓蚀性能研究
引用本文:刘忠运,李莉娜,张大椿,吴大伟. 新型咪唑啉缓蚀剂的合成及其缓蚀性能研究[J]. 精细化工中间体, 2009, 39(4): 39-43
作者姓名:刘忠运  李莉娜  张大椿  吴大伟
作者单位:长江大学油气钻采工程湖北省重点实验室,湖北,荆州,434023;天津理工大学化学化工学院,天津,300384
摘    要:合成了-种复合缓蚀剂YHX-4.研究了其在二氧化碳/硫化氢共存条件下的缓蚀性能。研究表明,在/7,(油酸):n(二乙烯三胺):n(硫脲):n(氯化苄)=1:1.4:1:1.2、成环反应最高温度220℃、成环时间8h;季铵化反应温度90℃、时间3h条件下可合成咪唑啉季铵盐缓蚀剂YHX-3,目标产物经红外表征。将YHX-3与自制的4种物质:炔氧甲基烷基苄基季铵盐(HPOMAQ)、丁炔二醇(BOZ)、磷酸三乙酯(TEP)、增效剂SA进行复配[m(YHX-3):m(BOZ):m(HPOMAQ):m(TEP):m(SA)=30:8:8:3:1]得缓蚀剂YHX-4,其在二氧化碳/硫化氢共存的腐蚀介质中静态缓蚀率大于92%。动态缓腐蚀率大于88%。

关 键 词:咪唑啉季铵盐  缓蚀剂  缓蚀率  合成

Research on the Synthesis and Anti-corrosive Performance of Novel Imidazoline Corrosion Inhibitors
LIU Zhang-yun,LI Lina,ZHANG Da-chun,WU Da-wei. Research on the Synthesis and Anti-corrosive Performance of Novel Imidazoline Corrosion Inhibitors[J]. Fine Chemical Intermediates, 2009, 39(4): 39-43
Authors:LIU Zhang-yun  LI Lina  ZHANG Da-chun  WU Da-wei
Affiliation:LIU Zhong-yun, LI Li-na, ZHANG Da-chun, WU Da-wei ( 1. Key Laboratory of Oil and Gas Drilling and Production Engineering, Yangtze University, Jinzhou 434023, China; 2. Chemistry and Chemical Engineering College, Tianjin University of Technology, Tianjin 300384, China)
Abstract:Compound YHX-4 was prepared and its corrosion inhibition properties were studied under the CO2/H2S coexistence conditions. Results indicated that the optimum conditions for synthesizing imidazoline quaternary-ammonium-salts corrosion inhibitor (YHX-3) were:n(oleic acid)∶n(diethylenetriamine)∶n (thiourea)∶n (benzylchloride)=1:1.4∶1∶1.2,the cyclization reaction lasted for 8 h at the highest temperature of 220 ℃, and then quaternized for 3 h at 90 ℃. The structure of the product was proved with infrared spectrum. Corrosion inhibitor YHX-4 was then composed of YHX-3 and other four self-made substances including HPOMAQ, BOZ, TEP and SA [m(YHX-3)∶m(BOZ)∶m(HPOMAQ)∶m(TEP)∶m(SA)=30∶8∶8∶3:1]. The efficiencies of its static and dynamic corrosion inhibition in the CO2/ H2S medium were more than 92% and 88%, respectively.
Keywords:imidazoline quaternary-ammonium-salt   corrosion inhibitor   corrosion efficiency   synthesis
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