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Carbon Nanotube‐Quantum Dot Nanohybrids: Coupling with Single‐Particle Control in Aqueous Solution
Authors:Antonio Attanzio  Andrei Sapelkin  Felice Gesuele  Arend van der Zande  William P. Gillin  Ming Zheng  Matteo Palma
Affiliation:1. Materials Research Institute and School of Biological and Chemical Sciences, Queen Mary University of London, London, UK;2. Materials Research Institute and School of Physics and Astronomy, Queen Mary University of London, London, UK;3. Department of Physics, University of Naples “Federico II,”, Napoli, Italy;4. Department of Mechanical Science and Engineering, University of Illinois at Urbana–Champaign, IL, USA;5. Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, MD, USA
Abstract:A strategy is reported for the controlled assembly of organic‐inorganic heterostructures consisting of individual single‐walled carbon nanotubes (SWCNTs) selectively coupled to single semiconductor quantum dots (QDs). The assembly in aqueous solution was controlled towards the formation of monofunctionalized SWCNT‐QD structures. Photoluminescence studies in solution, and on surfaces at the single nanohybrid level, showed evidence of electronic coupling between the two nanostructures. The ability to covalently couple heterostructures with single particle control is crucial for the design of novel QD‐based optoelectronic and light‐energy conversion devices.
Keywords:carbon nanotubes  nanocarbon hybrids  quantum dots  self‐assembly  single‐molecules
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