Emerging Prototype Sodium‐Ion Full Cells with Nanostructured Electrode Materials

Due to steadily increasing energy consumption, the demand of renewable energy sources is more urgent than ever. Sodium‐ion batteries (SIBs) have emerged as a cost‐effective alternative because of the earth abundance of Na resources and their competitive electrochemical behaviors. Before practical application, it is essential to establish a bridge between the sodium half‐cell and the commercial battery from a full cell perspective. An overview of the major challenges, most recent advances, and outlooks of non‐aqueous and aqueous sodium‐ion full cells (SIFCs) is presented. Considering the intimate relationship between SIFCs and electrode materials, including structure, composition and mutual matching principle, both the advance of various prototype SIFCs and the electrochemistry development of nanostructured electrode materials are reviewed. It is noted that a series of SIFCs combined with layered oxides and hard carbon are capable of providing a high specific gravimetric energy above 200 Wh kg^–1, and an NaCrO₂//hard carbon full cell is able to deliver a high rate capability over 100 C. To achieve industrialization of SIBs, more systematic work should focus on electrode construction, component compatibility, and battery technologies.