| 新型杂化单体4-(1-丙烯基)氧丁基缩水甘油醚的合成及光聚合性能研究 |
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| 引用本文： | 孙梦洲,何勇,李淑娟,聂俊.新型杂化单体4-(1-丙烯基)氧丁基缩水甘油醚的合成及光聚合性能研究[J].信息记录材料,2007,8(1):5-9. |
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| 作者姓名： | 孙梦洲 何勇 李淑娟 聂俊 |
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| 作者单位： | 北京化工大学,材料科学与工程学院,北京,100029 |
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| 摘 要： | 通过3步反应合成了一种新型杂化单体4-(1-丙烯基)氧丁基缩水甘油醚(POBGE)。使用傅立叶红外光谱和核磁共振仪对相应产物结构进行了表征。同时使用傅立叶实时红外(FT-RTIR)对该杂化单体的光聚合性能进行了研究。考察了引发剂种类,不同浓度光引发剂,不同光照强度对杂化单体的光聚合性能的影响。结果表明,光引发剂硫鎓盐的引发性能要优于碘鎓盐,随着光引发剂浓度以及光照强度的增大杂化单体双键及环氧基团的转化率都相应提高。
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| 关 键 词： | 杂化单体 光聚合 FT-RTIR |
| 文章编号： | 1009-5624-（2007）01-0005-05 |
| 收稿时间： | 2006-10-18 |
| 修稿时间： | 2006年10月18 |
The Synthesis and Cationic Photopolymerization Characteristics of 4- (1-propenyl) Oxybutyl Glycidyl Ether |
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| SUN Meng-zhou,HE Yong,LI Shu-juan,NIE Jun.The Synthesis and Cationic Photopolymerization Characteristics of 4- (1-propenyl) Oxybutyl Glycidyl Ether[J].Information Recording Materials,2007,8(1):5-9. |
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| Authors: | SUN Meng-zhou HE Yong LI Shu-juan NIE Jun |
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| Affiliation: | College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China |
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| Abstract: | A novel hybrid monomer 4-(1-propenyl)oxybutyl glycidyl ether(POBGE) was synthesized via three steps reaction.The product was characterized by Fourier Transform Infrared(FTIR) and 1 H-NMR spectroscopy.The photopolymerization characteristics of this monomer was investigated by Fourier Transform Real Time Infrared spectroscopy(FT-RTIR).The results indicated that the reactivity of triarylsufonium was better than the diarylliodonium.The final conversion of epoxy group and double bond were increased with increasing the initiator concentration and light intensity. |
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| Keywords: | FT-RTIR |
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