Monodispersed spherical colloids of Se@CdSe: synthesis and use as building blocks in fabricating photonic crystals |
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Authors: | Jeong Unyong Kim Jong-Uk Xia Younan Li Zhi-Yuan |
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Affiliation: | Department of Chemistry, University of Washington, Seattle, Washington 98195-1700, USA. |
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Abstract: | Monodispersed spherical core-shell colloids of Se@Ag(2)Se have been exploited as a chemical template to synthesize Se@CdSe core-shell particles using a cation-exchange reaction. A small amount of tributylphosphine could facilitate the replacement of Ag(+) by Cd(2+) in methanol at 50 degrees C to complete the conversion within 150 min. The orthorhombic structure of beta-Ag(2)Se changed to a well-defined wurtzite lattice for CdSe. The CdSe shells could be converted back to beta-Ag(2)Se by reacting with AgNO(3) in methanol at room temperature. Because of the uniformity in size and high refractive index associated with the Se@CdSe core-shell colloids, they could serve as a new class of building blocks to fabricate photonic crystals with wide and strong stop bands. |
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