| Synthesis of Composite Nanoparticles Bearing Epoxy Functional Groups：Encapsulation of Silica by Emulsion Polymerization of GMA |
| |
| 作者姓名： | ZENG Zhong YU Jian GUO Zhaoxia |
| |
| 作者单位： | Institute of Polymer Science and Engineering, Department of Chemical Engineering, School of Materials Science and Engineering, Tsinghua University, Beijing 10084, China |
| |
| 摘 要： | Poly （ glycidyl methacrylate ） / silica （PGMA/silica） composite nanoparticles , containing epoxy functional groups on the surface, were synthesized via emulsion polymerization. With batch process, high yield and binding efficiency （ both around 90% ） were achieved. The amount of crosslinked GMA was approximately 8wt%- 14wt% to the polymerized monomer. It was found that both the encapsulating ratio and the number of the original silica beads per composite particles altered with the amount of silica added. The obtained particles, with their average particle size of about 60- 70 nm, had a spherical shape and a clear core- shell structure.
|
| 关 键 词： | 聚甲基丙烯酸缩水甘油酯 硅 复合物纳米粒子 环氧官能团 乳液聚合 |
| 收稿时间： | 2005-04-25 |
| 修稿时间： | 2005-10-23 |
Synthesis of composite nanoparticles bearing epoxy functional groups: Encapsulation of silica by emulsion polymerization of GMA |
| |
| ZENG Zhong YU Jian GUO Zhaoxia.Synthesis of composite nanoparticles bearing epoxy functional groups: Encapsulation of silica by emulsion polymerization of GMA[J].Journal of Wuhan University of Technology. Materials Science Edition,2006,21(2):136-138. |
| |
| Authors: | Zeng Zhong Yu Jian Guo Zhaoxia |
| |
| Affiliation: | (1) Institute of Polymer Science and Engineering Department of Chemical Engineering, School of Materials Science and Engineering, Tsinghua University, 10084 Beijing, China |
| |
| Abstract: | Poly (glycidyl methacrylate)/silica (PGMA/silica) composite nanoparticles, containing epoxy functional groups on the surface, were synthesized via emulsion polymerization. With batch process, high yield and binding efficiency (both around 90%) were achieved. The amount of crosslinked GMA was approximately 8wt%-14wt% to the polymerized monomer. It was found that both the encapsulating ratio and the number of the original silica beads per composite particles altered with the amount of silica added. The obtained particles, with their average particle size of about 60-70 nm, had a spherical shape and a clear core-shell structure. |
| |
| Keywords: | epoxy functionalization composite nanoparticles |
| 本文献已被 CNKI 维普 万方数据 SpringerLink 等数据库收录！ |
