稻壳二氧化硅/环氧树脂纳米复合材料机械性能研究 |
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引用本文: | 刘学清,刘继延,朱虎义,甘艳梅,谢大海. 稻壳二氧化硅/环氧树脂纳米复合材料机械性能研究[J]. 塑料工业, 2009, 37(11) |
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作者姓名: | 刘学清 刘继延 朱虎义 甘艳梅 谢大海 |
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作者单位: | 江汉大学化学与环境工程学院,湖北,武汉,430056 |
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摘 要: | 将稻壳用10%的盐酸处理后在600℃焚烧得到纯度为99.3%的SiO_2,将SiO_2用偶联剂γ-氨丙基三乙氧基硅烷(KH550)改性后与环氧树脂(EP)复合,探讨了SiO_2质量分数在0~5%范围内复合材料的力学性能.研究结果显示:经硅烷偶联剂KH550改性后稻壳SiO_2粒子为无定形态,尺寸在30~50 nm且能显著提高环氧树脂的力学性能.当稻壳SiO_2质量分数为3%时,材料的拉伸性能以及弯曲性能的提高率最大,拉伸强度、拉伸模量、弯曲模量和弯曲强度的提高率分别为27.25%、6.54%、61.7%和24.56%.SEM研究结果显示:复合材料中SiO_2与基体树脂之间有较好的相容性.
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关 键 词: | 稻壳二氧化硅 环氧树脂 纳米复合材料 机械性能 |
Study of Mechanical Properties of Rice Husk Silica/Epoxy Resin Nanocomposites |
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Abstract: | Silica nanoparticles with purity of 99.3% were obtained by burning treated with the rice husk 10% HCl(v/v)at 600℃. SiO_2 was modified with coupling agent γ-glycidyloxipropyhrimethoxysilane (KH550), and then compounded with epoxy resin. Studied the mechanical properties of the nanocomposites when silica content was 0~5%. Results showed that after modification by KH550, the SiO_2 particles was amorphous ones, and the size ranged from 30~50 nm, and could increase the mechanical properties of the EP greatly. When the content of SiO_2 was 30 wt%, the increasing rate of tensile and flexural strength were the highest. The improvement in tensile strength , tensile modulus, flexural modulus and flexural strength were 27.25%, 6.54%, 61.7% and 24.56% respectively. Scanning electron microscopy(SEM)showed rice husk silica had good compatibility with epoxy resin in the nanocomposites. |
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Keywords: | Rice Husk Silica Epoxy Resin Nanocomposites Mechanical Properties |
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