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SPE膜电极及其在化学传感器中的应用
引用本文:陈霭璠,陈亮媛,崔梅生,罗瑞贤,Chungchiun LIU.SPE膜电极及其在化学传感器中的应用[J].中国化学工程学报,2001,9(2):186-189.
作者姓名:陈霭璠  陈亮媛  崔梅生  罗瑞贤  Chungchiun LIU
作者单位:[1]ChemistryDepartment,BeijingUniversityof-ChemicalTechnology,Beijing100029,China [2]DepartmentofChemicalEngineering,CaseWesternReserveUniversity,Cleveland,OH44106,U.S.A.
基金项目:Supported by the National Natural Science Foundation of China (No. 29875002) and the Natural Science Foundation of Beijing (No. 2002017).
摘    要:Abstract The structure and proton conducting mechanism of solid polymer electrolyte (SPE) are described. Since the conductivity of electrolyte is important in SPE electrochemical cell research and development, we investigate quantitatively the conductivity of Nation membrane and its dependence on temperature and relative humidity. Experimental results show that the conductivity of Nation membrane increases with temperature and relative humidity.We also reports on the preparation and development of SPE membrane electrode with the emphasis on the mixture pressing method and impregnation-reduction process to prepare SPE composite electrode assemblies and their application to electrochemical sensors. We also investigate and fabricate a potentiometric electrochemical sensor of hydrogen and ethylene to measure the hydrogen and ethylene partial pressure.

关 键 词:SPE  膜电极  化学传感器  应用  固体聚合电解  氢-乙烯传感器
修稿时间: 

SPE Membrane Electrode and Its Application to Chemical Sensor
CHEN Aifan,Cui Meisheng,CHEN Liangyuan.SPE Membrane Electrode and Its Application to Chemical Sensor[J].Chinese Journal of Chemical Engineering,2001,9(2):186-189.
Authors:CHEN Aifan  Cui Meisheng  CHEN Liangyuan
Affiliation:Chemistry Department, Beijing University of Chemical Technology, Beijing 100029, China Department of Chemical Engineering, Case Western Reserve University, Cleveland, OH 44106, U. S. A.
Abstract:The structure and proton conducting mechanism of solid polymer electrolyte (SPE) are described. Since the conductivity of electrolyte is important in SPE electrochemical cell research and development, we investigate quantitatively the conductivity of Nafion membrane and its dependence on temperature and relative humidity. Experimental results show that the conductivity of Nafion membrane increases with temperature and relative humidity. We also reports on the preparation and development of SPE membrane electrode with the emphasis on the mixture pressing method and impregnation-reduction process to prepare SPE composite electrode assemblies and their application to electrochemical sensors. We also investigate and fabricate a potentiometric electrochemical sensor of hydrogen and ethylene to measure the hydrogen and ethylene partial pressure.
Keywords:solid polymer electrolyte  composite membrane electrode  hydrogen and ethylene sensors
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