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活性炭吸附铂和钯的实验研究
引用本文:朱云,胡汉,郭淑仙.活性炭吸附铂和钯的实验研究[J].稀有金属,2001,25(6):474-477.
作者姓名:朱云  胡汉  郭淑仙
作者单位:昆明理工大学材料与冶金工程学院冶金系
摘    要:测定了活性炭吸附铂和钯的热效应;在盐酸溶液中为-41822和-12806J/mol,在氰化钠溶液中为-29116和-19470J/mol。测定了吸附等温线,其符合Freundlich等温式,吸附铂:lgQ炭=1.6565lgc溶液 2.1421;吸附钯:lgQ炭=1.7446lgc溶液 2.1266。研究了活性温度、离子强度和溶液的pH值对炭吸附铂和钯的影响。

关 键 词:活性炭  吸附  解吸    
文章编号:0258-7076(2001)06-0474-04
修稿时间:2001年3月1日

Experimental study on adsorption of platinum and palladium with active carbon
Zhu Yun,Hu Han and Guo Shuxian.Experimental study on adsorption of platinum and palladium with active carbon[J].Chinese Journal of Rare Metals,2001,25(6):474-477.
Authors:Zhu Yun  Hu Han and Guo Shuxian
Abstract:The adsorption heat of platinum and palladium with active carbon was determined,that are 41822, 12806 J/mol(in HCl solution) and 29 116, 19470 J/mol(in H_2SO_4 solution), respectively. The adsorption isothermal line with active c arbon was determined by experiment. It conforms with Freundlich adsorption isoth ermal equation that lg Q _C=1 6565 lg c _ s 2 1421 and lg Q _C=1 7446 lg c _ s 2 1266.The influence factors for activated temperature, ion intensity and pH were researched.
Keywords:Active carbon  Adsorption  Desorption  Platinum  Palladium  
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