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双组分水性聚氨酯哑光清漆的制备
引用本文:李芝华,王亚,周斌,周子鹄,李珍. 双组分水性聚氨酯哑光清漆的制备[J]. 电镀与涂饰, 2012, 31(4): 61-64
作者姓名:李芝华  王亚  周斌  周子鹄  李珍
作者单位:1. 中南大学材料科学与工程学院,湖南长沙410083;中南大学有色金属材料科学与工程教育部重点实验室,湖南长沙410083
2. 中南大学材料科学与工程学院,湖南长沙410083;中南大学有色金属材料科学与工程教育部重点实验室,湖南长沙410083;广州秀珀化工股份有限公司,广东广州511495
3. 广州秀珀化工股份有限公司,广东广州,511495
摘    要:采用拜耳公司的水性羟基丙烯酸树脂乳液和聚异氰酸酯固化剂制备了一种聚氨酯哑光清漆。通过实验研究确定了两种羟基树脂组分的混拼比例为48.00%的BayhydrolXP2546和23.00%的BayhydrolXP2542,NCO与OH的摩尔比为1.6。讨论了消光剂加入量与漆膜光泽的变化关系,当消光剂的质量分数为2.4%时,所制备的聚氨酯哑光清漆具有硬度高,耐磨性与耐候性好,光泽低等特点,综合性能优异。

关 键 词:水性聚氨酯  清漆  哑光  羟基丙烯酸树脂  聚异氰酸酯固化剂

Preparation of two-component waterborne semi-gloss polyurethane varnish
LI Zhi-hua , WANG Ya , ZHOU Bin , ZHOU Zi-hu , LI Zhen. Preparation of two-component waterborne semi-gloss polyurethane varnish[J]. Electroplating & Finishing, 2012, 31(4): 61-64
Authors:LI Zhi-hua    WANG Ya    ZHOU Bin    ZHOU Zi-hu    LI Zhen
Affiliation:School of Materials Science and Engineering,Central South China of University,Changsha 410083,China
Abstract:A waterborne semi-gloss polyurethane varnish was prepared by using waterborne hydroxyl acrylic resin emulsion and polyisocyanate curing agent provided by Bayer MaterialScience.The mixing proportion of two types of hydroxyl resins was ascertained by test as follows:48.00% Bayhydrol XP 2546 and 23.00% Bayhydrol XP 2542.The molar ratio of NCO to OH is 1.6.The relationship between the amount of matting agent and film luster was discussed.The semi-gloss polyurethane varnish prepared with 2.4wt% matting agent has high hardness,excellent wear and weather resistance,and low glossiness,presenting a good comprehensive performance.
Keywords:waterborne polyurethane  varnish  semi-gloss  hydroxyl acrylic resin  polyisocyanate curing agent
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