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高分子纤维增韧SiO_2气凝胶复合材料的制备
引用本文:姜小青,王丹,姚建曦,毛丹,邢朝建,赖小勇. 高分子纤维增韧SiO_2气凝胶复合材料的制备[J]. 稀有金属材料与工程, 2009, 38(Z2)
作者姓名:姜小青  王丹  姚建曦  毛丹  邢朝建  赖小勇
作者单位:1. 中国科学院过程工程研究所,北京,100080;中国科学院研究生院,北京,100049
2. 中国科学院过程工程研究所,北京,100080
基金项目:国家自然科学基金面上项目,中国科学院创新项目 
摘    要:以正硅酸乙酯为硅源,乙醇和水为溶剂,芳纶纤维为增强相,通过溶胶凝胶及常压干燥等步骤,实现了芳纶增韧SiO_2气凝胶复合材料的非超临界制备.采用扫描电镜、吸附-脱附等分析手段及热导率测试对所得气凝胶样品进行结构分析和性质表征.结果表明,调节反应体系的各反应参数可以获得具有不同外形、密度及热导率的复合材料;所得气凝胶平均孔径约为10~20 nm,比表面积可达1000 m~2/g,可望在隔热材料等领域得到应用.

关 键 词:SiO_2气凝胶  纤维增韧  隔热

Preparation of SiO_2 Aerogels Heat Insulation Composites Reinforced by Aramid Fiber
Jiang Xiaoqing,Wang Dan,Yao Janxi,Mao Dan,Xing Chaojian,Lai Xiaoyong. Preparation of SiO_2 Aerogels Heat Insulation Composites Reinforced by Aramid Fiber[J]. Rare Metal Materials and Engineering, 2009, 38(Z2)
Authors:Jiang Xiaoqing  Wang Dan  Yao Janxi  Mao Dan  Xing Chaojian  Lai Xiaoyong
Affiliation:Jiang Xiaoqing1,2,Wang Dan1,Yao Janxi1,Mao Dan1,Xing Chaojian1,Lai Xiaoyong1 (1. Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China) (2. Graduate University of Chinese Academy of Sciences,Beijing 100049,China)
Abstract:A high malleable silica aerogel composite was prepared by acid/base two step sol-gel process in alcohol-water mixed solvents with tetraethoxysilane (TEOS) as precursor, aramid fiber as reinforcement, followed by ambient-dried method. The microstructure and properties were characterized by FESEM, BET and so on. The results indicated that the composites with different density, contour and thermal conductivity can be prepared by changing the reaction parameters. The average pore size of aerogel is 10~20 nm, specific surface area is more than 1000 m~2/g, which is hopeful to be applied in heat insulation field.
Keywords:silica aerogel  fiber reinforced  heat insulation
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