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温度和酸浓度对铁在盐酸溶液中析氢磁致过电位的影响
引用本文:吕战鹏,陈俊明.温度和酸浓度对铁在盐酸溶液中析氢磁致过电位的影响[J].中国腐蚀与防护学报,1995,15(4):303-307.
作者姓名:吕战鹏  陈俊明
作者单位:中国科学院上海冶金研究所
摘    要:提出了磁致过电位面的表达式。用动电位扫描法研究了0.4T磁场下纯铁在不同温度(25,40,60℃)和不同浓度的盐酸(0.05,0.2,1mol/L)中的阴极极化曲线,得出与温度和盐酸浓度的关系。以水合离子作用导致双电层结构改变的观点解释了温度和盐酸浓度对的影响。

关 键 词:铁在盐酸中腐蚀  磁场影响  磁致过电位  析氢反应  
收稿时间:1995-08-25

EFFECTS OF TEMPERATURE AND ACID CONCENTRATION ON MAGNETIC-INDUCED HYDROGEN EVOLUTION OVERPOTENTIAL OF IRON IN HYDROCHLORIC ACID SOLUTIONS
Lu Zhanpeng,Chen Junming.EFFECTS OF TEMPERATURE AND ACID CONCENTRATION ON MAGNETIC-INDUCED HYDROGEN EVOLUTION OVERPOTENTIAL OF IRON IN HYDROCHLORIC ACID SOLUTIONS[J].Journal of Chinese Society For Corrosion and Protection,1995,15(4):303-307.
Authors:Lu Zhanpeng  Chen Junming
Abstract:A formula for magnotic-induced hydrogen evolution overpotential was proposed.Cathodic polarization curves for iron in hydrochloric acid solution of different concentrations (0.05,0.2,1 mol/L) at differeat temperstures (25,40,60℃) were measured in the presence of magnetic field of 0.4T (tesla).The dependence of on temperature and hydrochloric acid concentration was obtained. Such a relationship was interpreted from the point of view that varistion of hydrogen ion hydration caused by changes in environmeat might alter the structure of electric double layer.
Keywords:Corrosion of iron in hydrochloric acid  Effect of magnetic field  Magnetic-induced overpotential  Hydrogen evolution
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