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Upconversion emission of SrYbF5:Er3+nanosheets modified by Tm3+ions
引用本文:刘晴,颜晓红,陈远,王祥夫.Upconversion emission of SrYbF5:Er3+nanosheets modified by Tm3+ions[J].中国稀土学报(英文版),2013,31(11):1053-1058.
作者姓名:刘晴  颜晓红  陈远  王祥夫
作者单位:[1]College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China [2]School of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210046, China
基金项目:Project supported by National Natural Science Foundation of China (51032002), Key Project of the National High Technology Re- search and Development Program ("863" Program) of China (2011AA050526), Science and Technology Support Plan of Jiangsu Province (BE2011191) and Funding of Jiangsu Innovation Program for Graduate Education (CXZZ13_0143)
摘    要:Through a hydrothermal route, the Er3+and Tm3+co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spec-tra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3+ions centered at 474 nm (1G4→3H6), 679 nm (3F2→3H6), 699 nm (3F3→3H6), 803 nm (3H4→3H6) and emissions of Er3+ions centered at 522 nm (2H11/2→4I15/2), 543 nm (4S3/2→4I15/2), 654 nm (4F9/2→4I15/2) were observed. The upconversion emissions of Er3+ions were adjusted by the concentration of Tm3+ions. The energy transfer mechanisms among Er3+-Yb3+-Tm3+in SrYbF5 nanosheets were discussed.

关 键 词:上转换发光  离子修饰  纳米  扫描电子显微镜  X射线衍射  X射线光谱  铒离子  能量色散
收稿时间:27 May 2013
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