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Synthesis and luminescence characteristics of Li2Y4-xEux(WO4)7-y(MoO4)y red-emitting phosphor for white LED
引用本文:茹晶晶,郭飞云,陈建中.Synthesis and luminescence characteristics of Li2Y4-xEux(WO4)7-y(MoO4)y red-emitting phosphor for white LED[J].中国稀土学报(英文版),2013,31(11):1059-1062.
作者姓名:茹晶晶  郭飞云  陈建中
作者单位:[1]Department of Chemistry, Ningde Normal University, Ningde 352100, China [2]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou350108, China
基金项目:Project supported by Fujian Provincial Department of Education Project (JA13331)Acknowledgement: Authors would like to thank the financial support from Ningde Science and Technology Project (20110115) and Service Haixi Construction Project of Ningde Normal University (2011 H206).
摘    要:Li2Y4-xEux(WO4)7-y(MoO4)y red-emitting phosphors were synthesized by solid state reaction and characterized by powder X-ray diffraction (XRD) and photoluminescence (PL) spectrum. The excitation spectra showed that the phosphors could be efficiently excited by near-UV light of 395 nm. When the relative molar ratio of Mo/W was 7:0, and the optimum doped concentration of Eu3+was 2.8 mol, the phosphor showed strong red emission lines at 615 nm corresponding to the forced electric dipole 5D0→7F2 transition of Eu3+. Compared with Na2Y2Eu2(MoO4)7 and K2Y2Eu2(MoO4)7, the fluorescence intensity of Li2Y1.2Eu2.8(MoO4)7 phosphor was the strongest. The CIE chromaticity coordinates of Li2Y1.2Eu2.8(MoO4)7 phosphor was calculated to be (0.66, 0.34).

关 键 词:红色荧光体  白色LED  发光特性  合成  X射线粉末衍射    最佳掺杂浓度  激发光谱
收稿时间:7 June 2013
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