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n-CHA/HDPE和n-CHA/gHDPE生物复合材料的界面表征
引用本文:左奕,李玉宝,韩劲,陈世途,杨维虎,吴兰,王华楠. n-CHA/HDPE和n-CHA/gHDPE生物复合材料的界面表征[J]. 材料工程, 2006, 0(12): 50-53,57
作者姓名:左奕  李玉宝  韩劲  陈世途  杨维虎  吴兰  王华楠
作者单位:1. 四川大学,纳米生物材料研究中心,成都,610064;四川大学,分析测试中心,成都,610064;科技部国家纳米生物医学材料产业化孵化基地,成都,610041
2. 四川大学,纳米生物材料研究中心,成都,610064;四川大学,分析测试中心,成都,610064
3. 四川大学,分析测试中心,成都,610064
摘    要:采用常压共溶复合工艺,在溶液体系中合成了分散均匀的n-CHA/HDPE,n-CHA/gHDPE两种生物功能材料,利用各种检测手段分析复合材料的界面结合状态.结果表明:n-CHA/HDPE复合材料是简单物理共混;而n-CHA/gHDPE复合材料则具有稳定的界面结合,n-CHA与gHDPE两相界面间有化学键形成.

关 键 词:生物功能材料  纳米碳酸羟基磷灰石  界面  化学键合
文章编号:1001-4381(2006)12-0050-04
收稿时间:2005-10-25
修稿时间:2005-10-252006-03-09

Characterization on Interface of n-CHA/HDPE and n-CHA/gHDPE Composite for Biomaterials
ZUO Yi,LI Yu-bao,HAN Jin,CHEN Shi-tu,YANG Wei-hu,WU Lan,WANG Hua-nan. Characterization on Interface of n-CHA/HDPE and n-CHA/gHDPE Composite for Biomaterials[J]. Journal of Materials Engineering, 2006, 0(12): 50-53,57
Authors:ZUO Yi  LI Yu-bao  HAN Jin  CHEN Shi-tu  YANG Wei-hu  WU Lan  WANG Hua-nan
Affiliation:1 Research Center for Nano-biomaterials, Sichuan University, Chengdu 610064, China; 2 Analytical Testing Center, Sichuan University, Chengdu 610064, China; 3 National Incubation for Nano-biomaterials Industrialization of MST, Chengdu 610041, China
Abstract:Two functionalized biomaterials were prepared in solution system by a new method at normal atmosphere.They were nano-carbonate hydroxyapatite reinforced high density polyethylene composite(n-CHA/HDPE) and n-CHA reinforced maleic anhydride grafted high density polyethylene composite(n-CHA/gHDPE).The interface of composites was analyzed in terms of burning test,TEM,IR,XRD and Molau testing.The results showed that n-CHA/HDPE composite was simple mechanical mixed,but n-CHA/gHDPE composite had stable interface connection based on the chemical bonding as esterification and hydrogen bonding formed between the two phases.
Keywords:functionalized biomaterial    nano-carbonate hydroxyapatite    interface    chemical bonding
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