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Hydrogen-induced CO2 formation from ethylene deposits on Pt during consecutive O2 and H2 exposures
Authors:Petronella Norberg  Ingemar Lundström  Lars-Gunnar Ekedahl
Affiliation:(1) Department of Physics and Measurement Technology, Linköping University, 581 83 Linköping, Sweden
Abstract:The oxidation of C2H4 deposits on polycrystalline Pt when exposed to consecutive O2 and H2 pulses at room temperature has been investigated in a long (L = 36 mm), shallow (d = 600–700 nm) micromachined glass–SiO2–Pt channel. Hydrogen-induced CO2 formation from species accumulated on the Pt surface was observed. Frequent switching of the O2/H2 exposure pulses was found to increase the efficiency of the oxidation of the carbonaceous deposits markedly. The observations may be of general interest for the regeneration of contaminated catalysts.
Keywords:catalysis  carbonaceous contaminants  regeneration of catalyst  ethylene  carbon monoxide  carbon dioxide  platinum  hydrogen  oxygen
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