Molecular‐Scale Hybridization of Clay Monolayers and Conducting Polymer for Thin‐Film Supercapacitors |
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| Authors: | Jingwen Zhao Simin Xu Kristina Tschulik Richard G Compton Min Wei Dermot O'Hare David G Evans Xue Duan |
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| Affiliation: | 1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, P. R. China;2. Physical and Theoretical Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford, UK;3. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Oxford, UK |
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| Abstract: | Development of electrode materials with well‐defined architectures is a fruitful and profitable approach for achieving highly‐efficient energy storage systems. A molecular‐scale hybrid system is presented based on the self‐assembly of CoNi‐layered double hydroxide (CoNi‐LDH) monolayers and the conducting polymer (poly(3,4‐ethylene dioxythiophene):poly(styrene sulfonate), denoted as PEDOT:PSS) into an alternating‐layer superlattice. Owing to the homogeneous interface and intimate interaction, the resulting CoNi‐LDH/PEDOT:PSS hybrid materials possess a simultaneous enhancement in ion and charge‐carrier transport and exhibit improved capacitive properties with a high specific capacitance (960 F g–1 at 2 A g–1) and excellent rate capability (83.7% retention at 30 A g–1). In addition, an in‐plane supercapacitor device with an interdigital design is fabricated based on a CoNi‐LDH/PEDOT:PSS thin film, delivering a significantly enhanced energy and power output (an energy density of 46.1 Wh kg–1 at 11.9 kW kg–1). Its application in miniaturized devices is further demonstrated by successfully driving a photodetector. These characteristics demonstrate that the molecular‐scale assembly of LDH monolayers and the conducting polymer is promising for energy storage and conversion applications in miniaturized electronics. |
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| Keywords: | conducting polymers layered double hydroxides molecular scale superlattice thin‐film supercapacitors |
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