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| 新型锂电池正极材料——蒽醌/介孔炭寄生型复合物 | |
| 引用本文： | 赵磊,王维坤,王安邦,余仲宝,陈实,杨裕生.新型锂电池正极材料——蒽醌/介孔炭寄生型复合物[J].功能材料,2011,42(7). |
| 作者姓名： | 赵磊 王维坤 王安邦 余仲宝 陈实 杨裕生 |
| 作者单位： | 1. 北京理工大学化工与环境学院,北京,100081 2. 防化研究院军用化学电源研究与发展中心,北京,100191 3. 北京理工大学化工与环境学院,北京100081 防化研究院军用化学电源研究与发展中心,北京100191 |
| 基金项目： | 国家重点基础研究发展计划(973计划)资助项目(2009CB220100) |
| 摘 要： | 将9,10-蒽醌（AQ）通过升华法填充在介孔炭（MC）的孔中,制备出蒽醌/介孔炭寄生型复合物。用TG/DSC、SEM、氮吸附等方法对介孔炭及复合材料进行了表征,应用恒流充放电、循环伏安法、交流阻抗等测试手段对复合材料的电化学性能进行了测试。结果表明炭/醌复合电极的比容量和循环性能较蒽醌电极有了很大程度的提高。其中蒽醌填充量为75%的复合材料首次放电比容量达到216mAh/g,50次循环之后,比容量仍有76mAh/g,是蒽醌电极比容量的2倍。 |
| 关 键 词： | 介孔炭 寄生复合材料 有机物正极材料 电化学性能 |
A novel MC/AQ parasitic composite as cathode material for lithium battery |
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| ZHAO Lei,WANG Wei-kun,WANG An-bang,YU Zhong-bao,CHEN Shi,YANG Yu-sheng.A novel MC/AQ parasitic composite as cathode material for lithium battery[J].Journal of Functional Materials,2011,42(7). | |
| Authors: | ZHAO Lei WANG Wei-kun WANG An-bang YU Zhong-bao CHEN Shi YANG Yu-sheng |
| Affiliation: | ZHAO Lei1,WANG Wei-kun2,WANG An-bang2,YU Zhong-bao2,CHEN Shi1,YANG Yu-sheng1,2(1.School of Chemical Engineering and Environment,Beijing Institute of Technology,Beijing 100081,China,2.Military Power Sources Research and Development Center,Research Institute of Chemical Defense,Beijing 100191,China) |
| Abstract: | The mesoporous carbon(MC)/AQ parasitic composite was synthesized by filling 9,10-anthraquinone into pores of MC with sublimation.The composite was charactered by the methods of TDA/DSC,SEM and N2 adsorption.The electrochemical performance of the composite was investigated by the methods of galvanostatic discharge/charge and cyclic voltammetry.The results indicated that the specific capacity and cycle life of the composite was increased.The initial discharge specific capacity of the composite(75% AQ containe... |
| Keywords: | mesoporous carbon MC/AQ parasitic composite organic cathode materials electrochemical performance |
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