Synthesis and characterization of polyamides based on dimer acid |
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Authors: | Wenzhi Wang Zhifang Zhang Meiyun Xu Yonghua Zhang |
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Affiliation: | (1) College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, China |
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Abstract: | A series of dimer acid-based polyamides were synthesized by melt-polycondensation of dimer acid and various aromatic diamines,
and were characterized by Fourier transform infrared spectrum (FT-IR) and nuclear magnetic resonance (1H NMR). The physical properties of the polyamides, such as glass transition temperature, melting temperature, decomposition
temperature and mechanical properties were also investigated. The polyamides’ intrinsic viscosity ranges from 1.8 dL·g−1 to 2.2 dL·g−1, and the melting temperature ranges from 140 °C to 181 °C. The glass transition temperatures, observed from dynamic mechanical
analysis, fall in the range of 34.8–48.2 °C. The physical and mechanical properties of the resultant polyamides are similar
to those of the PA1212. The heat resistance and mechanical properties of poly (4, 4′-diphenylsulfone dimeramide) (PSD) and
poly(4, 4′-diphenyl dimeramide) (PPDI) are comparable to those of PA1212. |
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Keywords: | polyamides dimer acid polycondensation aromatic diamines |
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