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On the mechanism of CO adsorption on a silica‐supported ruthenium catalyst
Authors:Margarita Kantcheva  Safak Sayan
Affiliation:(1) Department of Chemistry, Bilkent University, 06533 Bilkent, Ankara, Turkey
Abstract:The adsorption of CO at room temperature on a Ru/SiO2 catalyst has been studied by means of FTIR spectroscopy. Spectral evidence for formation of water molecules and a quantity of very dispersed ruthenium on the catalyst surface during CO adsorption was found. On the basis of these experimental results a new reaction scheme for the interaction of CO with a silica‐supported ruthenium catalyst is proposed. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:silica‐  supported ruthenium  CO adsorption  morphology change  mechanism
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