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芳香族硝基化合物改性煤沥青研究
引用本文:邱莉莉,许斌,惠大陆,田钮,黄艳. 芳香族硝基化合物改性煤沥青研究[J]. 炭素技术, 2012, 31(4): 1-6
作者姓名:邱莉莉  许斌  惠大陆  田钮  黄艳
作者单位:武汉科技大学 化学工程与技术学院,湖北武汉,430081
摘    要:以煤沥青为原料,通过添加不同含量的芳香族硝基化合物对煤沥青进行改性处理,采用TG、CO2反应性、XRD和SEM对改性沥青焦进行表征。结果表明,芳香族硝基化合物有效地促进了煤沥青在炭化过程中的焦化缩聚,使产物沥青焦结构更加致密,并在一定程度上改变了沥青焦的氧化行为,从而显著提高了沥青黏结焦的抗氧化性能。

关 键 词:煤沥青  芳香族硝基化合物  改性  抗氧化性能

Modification of coal tar pitch with aromatic nitro-compounds
QIU Li-li , XU Bin , HUI Da-liu , TIAN Niu , HUANG Yan. Modification of coal tar pitch with aromatic nitro-compounds[J]. Carbon Techniques, 2012, 31(4): 1-6
Authors:QIU Li-li    XU Bin    HUI Da-liu    TIAN Niu    HUANG Yan
Affiliation:(College of Chemical Engineering and Technology,Wuhan University of Science and Technology,Hubei Wuhan 430081,China)
Abstract:Coal tar pitch was modified by adding different kinds of aromatic nitro-compounds.Modified pitch cokes were characterized by using TG,CO2 reactivity,XRD and SEM measurements.The results show that nitro-compounds substantially enhance coking condensation of coal tar pitch which leads to the formation of denser pitch coke.Nitro-compounds effectively changed the oxidation behavior of modified pitch coke.The oxidation resistance of modified pitch coke has been evidently improved.
Keywords:Coal tar pitch  aromatic nitro-compound  modification  oxidation resistance
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