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Low formaldehyde emission,fast pressing,pine and pecan tannin adhesives for exterior particleboard
Authors:A. Pizzi  J. Valenezuela  C. Westermeyer
Affiliation:1. Dept. of Chemistry, University of the Witwatersrand, Wits 2050, Private Bag 3, Johannesburg, South Africa
2. Quimicos Coronel (Masisa), Conceptión, Chile
Abstract:Exterior grade particleboard satisfying the requirements of the V100 test, of formaldehyde emission well within the emission standard E1 class, and of pressing times as fast as 8.5 sec/mm can be produced at higher moisture contents using fast-reacting non-modified and non-fortified procyanidin/prodelphinidin tannin extracts such as pine bark tannin extract and pecan nut pith tannin extract. Such results, under the conditions reported are not achieved with the slower reacting tannins traditionally associated with the practice of tannin adhesives. The results reported establish that the faster is the reaction of the tannin with formaldehyde, the lower is the amount of formaldehyde needed to achieve V100 standard, the lower is the formaldehyde emission, the faster is the pressing time achievable and the higher is the tolerance of the adhesive to high moisture content of the resinated wood particles.
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