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钒对18Cr-2Mo铁素体不锈钢性能的影响
引用本文:李达岗,江来珠,金学军,王治宇,许海刚.钒对18Cr-2Mo铁素体不锈钢性能的影响[J].钢铁研究学报,2013,25(2):43-47.
作者姓名:李达岗  江来珠  金学军  王治宇  许海刚
作者单位:1. 上海交通大学材料科学与工程学院,上海200240;宝山钢铁股份有限公司研究院,上海201900
2. 宝山钢铁股份有限公司研究院,上海,201900
3. 上海交通大学材料科学与工程学院,上海,200240
基金项目:十二五国家科技支撑计划项目(2012BAE04B02)
摘    要: 利用Thermo-Calc热力学软件、扫描电子显微镜、X射线衍射仪及透射电镜等分析方法,研究了不同钒含量对单铌稳定18Cr-2Mo铁素体不锈钢微观组织、力学性能和点腐蚀性能的影响规律。结果表明:添加钒后的析出相主要是NbC和VN,弥散分布于晶内和晶界,其中NbC的尺寸为100~250nm;随着钒含量的增加,试验钢的晶粒尺寸及屈服强度变化不明显,而冲击韧性及点腐蚀性能逐步得到改善和提高,当wV=0.36%时,钢的韧脆?湮露扔稍嫉?10℃下降至-30℃,点腐蚀电位由0.38V提高至0.42V。

关 键 词:铁素体不锈钢  钒微合金化  微观组织  冲击韧性  点腐蚀性能   

Effect of Vanadium on Properties of 18Cr-2Mo Ferritic Stainless Steel
LI Da-gang,JIANG Lai-zhu,JIN Xue-jun,WANG Zhi-yu,XU Hai-gang.Effect of Vanadium on Properties of 18Cr-2Mo Ferritic Stainless Steel[J].Journal of Iron and Steel Research,2013,25(2):43-47.
Authors:LI Da-gang  JIANG Lai-zhu  JIN Xue-jun  WANG Zhi-yu  XU Hai-gang
Affiliation:1. School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai 200240, China ;2. Baosteel Research Institute, Baoshan Iron and Steel Co, Ltd, Shanghai 201900, China
Abstract:Thermo-Calc software, scanning electron microscope (SEM), X-ray diffraction (XRD) and transmission electron microscope (TEM) were used to investigate the effect of vanadium (V) on the microstructure, mechanical properties and pitting corrosion resistance of 18Cr-2Mo ferritic stainless steel stabilized by niobium (Nb). The results show that the precipitates are mainly composed of NbC and VN which are dispersed in the intragranular and grain boundary, and the size of most of NbC particles is in the range from 100 to 250nm. The grain size and yield strength of materials nearly keep the same with different V addition amount under the condition of ultra-low C and N content, while the impact toughness and pitting resistance are improved gradually with the increasing of V. With the addition of 0.36%V (mass fraction), the ductile to brittle transition temperature (DBTT) of the steel is decreased from -10 to -30℃, and the pitting potential (Ep) is improved from 0.38 to 0.42V.
Keywords:ferritic stainless steel  V microalloying  microstructure  impact toughness  pitting resistance
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