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Growth and Faraday rotation characteristics of TbVO4 crystals
Affiliation:1. Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Department of Physics, Shanghai Normal University, Shanghai 200234, China;1. Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov str., Nizhny Novgorod, Russia;2. G.G. Devyatykh Institute of Chemistry of High-Purity Substances of the Russian Academy of Sciences, 49 Tropinin str., Nizhny Novgorod, Russia
Abstract:TbVO4 (TV) single crystals with dimensions of 18 × 18 × 16 mm3 were grown by Czochralski method under different atmosphere. XPS studies revealed the presence of V4+ and Tb4+ in TV crystal grown at 99.9% N2 atmosphere, which caused a wide absorption peak centered at 950 nm in the transmission spectrum. TV crystal grown at 80% N2 + 20% CO2 mixed atmosphere has high transmittance at 600–1500 nm waveband. Faraday rotation spectra of TV crystal were measured. TV crystal has a larger Faraday rotation than terbium gallium garnet (TGG) crystal at 500–1500 nm waveband.
Keywords:Rare-earth vanadates  Czochralski method  Faraday rotation
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