Preparation, microstructure and electrical properties of Li1.4Al0.4Ti1.6(PO4)3 nanoceramics

NASICON-type Li_1.4Al_0.4Ti_1.6(PO₄)₃ solid electrolytes were prepared by various processes, such as crystallization of glasses, spark plasma sintering (SPS) and conventional sintering process from nanosized precursor powders synthesized by a sol–gel route. The experimental results showed that grain size and relative density were the main factors determining the ionic conductivity of the bulk materials. The SPS technique produced ceramics with nearly 100% of the theoretical density. Maximum room temperature conductivities, 1.39?×?10^?3 S cm^?1 and 1.12?×?10^?3 S cm^?1 of grain boundary conductivity and total conductivity, respectively were obtained which were the highest values for Li⁺ inorganic oxide conductors as reported. Crystallization of ceramics from a glass was also certified as a favorable route to fabricate a bulk material with high conductivity.