Intrinsic kinetics of the hydrogen reduction of Cu2S |
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Authors: | H Y Sohn S Won |
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Affiliation: | (1) Department of Metallurgy and Metallurgical Engineering, University of Utah, 84112-1183 Salt Lake City, UT;(2) Department of Metallurgy and Metallurgical Engineering, University of Utah, 800 East Pima Mine Road, 85725 Tucson, AZ |
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Abstract: | Intrinsic kinetics of the hydrogen reduction of cuprous sulfide (Cu2S) have been measured. Experiments were carried out in the temperature range 823 to 1023 K using a thermogravimetric analysis
method. The reaction was studied in detail using both thin pellets and powder samples. The reaction followed first-order kinetics
with respect to the solid reactant concentration as well as the hydrogen concentration. An activation energy of 92.0 kJ/mol
(22.0 kcal/g-mole) was obtained for the reaction. Copper produced from the reaction formed filaments which sintered above
about 1000 K.
Is now Senior Metallurgist with Cyprus Metallurgical Process Corporation |
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