Alkane conversion over Pd/SAPO molecular sieves: influence of acidity, metal concentration and structure |
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Authors: | M Hchtl A Jentys H Vinek |
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Affiliation: | Institute of Physical Chemistry and Theoretical Chemistry, University of Technology, Vienna, Getreidemarkt 9/156, A-1060 Vienna, Austria |
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Abstract: | The activity and selectivity for the isomerization of heptanes over Pd-loaded SAPO molecular sieves with AEL and AFI structure were investigated. By synthesis of the AEL molecular sieves from Al-isopropoxide, the acid site concentration could be controlled by the amount of silicon in the synthesis gel. The resulting concentration of SiAl–OH groups ranged from 0.07 to 0.3 mmol/g, exhibiting the same acid strength, independent from the acid site concentration. Catalysts were impregnated with 0.1–2 wt.% Pd. The activity increased with increasing Pd content up to a Pd to acid site ratio of 0.02–0.03. Above this value, the metal loading did not influence the activity. A further enhancement of the activity was possible by increasing the number of SiAl–OH acid sites. The selectivity to isomerization was constant for the catalysts with an acid site concentration >0.19 mmol/g. The catalysts synthesized from Al-isopropoxide showed a lower activity compared to the catalysts synthesized from aluminum oxide, probably due to diffusional restrictions caused by the formation of polycrystalline agglomerates. |
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Keywords: | Alkane isomerization SAPO-5 SAPO-11 Acid site concentration Metal loading |
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