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一种潜在的激光制冷介质-罗丹明B掺杂PMMA
引用本文:吴云龙,熊玉峰,房晖.一种潜在的激光制冷介质-罗丹明B掺杂PMMA[J].功能材料与器件学报,2004,10(3):383-386.
作者姓名:吴云龙  熊玉峰  房晖
作者单位:1. 中国科学院理化技术研究所,北京,100080;中国科学院研究生院,北京,100039
2. 中国科学院理化技术研究所,北京,100080
3. 中国科学院安徽光学精密机械研究所,合肥,230031
基金项目:国家自然科学基金资助(No.19974050)
摘    要:报道了罗丹明B掺杂PMMA材料制作过程及材料吸收和荧光光谱实验。吸收光谱表明,PMMA样品从紫外到近红外范围存在较小的吸收。罗丹明B/PMMA样品吸收光谱主要反映罗丹明B的吸收特征,其吸收峰中心波长位于550nm。荧光光谱显示,以630nm激发,反斯托克斯荧光峰位于595nm,能量差为0.11eV。该材料辐射反斯托克斯荧光,可用于激光制冷领域的研究。

关 键 词:激光制冷  反斯托克斯荧光  罗丹明B  PMMA  掺杂  制冷介质
文章编号:1007-4252(2004)03-0383-04
修稿时间:2003年9月27日

Rhodamine B doped PMMA-A potential material in laser cooling of solid
WU Yun-long,XIONG Yu-feng,FANG Hui.Rhodamine B doped PMMA-A potential material in laser cooling of solid[J].Journal of Functional Materials and Devices,2004,10(3):383-386.
Authors:WU Yun-long    XIONG Yu-feng  FANG Hui
Affiliation:WU Yun-long1,2,XIONG Yu-feng1,FANG Hui3
Abstract:Through the comparative study on the solid solutions of the Rhodmine B in PMMA, theyare found to be effective to produce fluorescence. Spectrum analysis by fluorescence spectrophotometerreveals that the materials appear to produce anti-stokes fluorescence peak with excitation sources atwavelengths longer than those corresponding to the peak of the luminescent bend. This means fluores-cence photons have redundant energy than pumping photons. That is to say that the Rhodamine B-doped PMMAs are potential material for laser cooling. One of the materials we proposed is solid solu-tion of Rhodamine B in PMMA. It is excited at 630nm and produced fluorescence peak about 595nm, and has energy difference of 0.11eV.
Keywords:laser cooling  anti-stokes fluorescence  Rhodamine B  PMMA
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