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铜合金表面激光诱导原位反应制备颗粒增强Co基复合合金涂层
引用本文:陈岁元,王建访,刘常升,梁京. 铜合金表面激光诱导原位反应制备颗粒增强Co基复合合金涂层[J]. 复合材料学报, 2008, 25(4): 126-130
作者姓名:陈岁元  王建访  刘常升  梁京
作者单位:东北大学,材料各向异性与织构教育部重点实验室,沈阳,110004;东北大学,材料各向异性与织构教育部重点实验室,沈阳,110004;东北大学,材料各向异性与织构教育部重点实验室,沈阳,110004;东北大学,材料各向异性与织构教育部重点实验室,沈阳,110004
基金项目:国家自然科学和宝钢联合基金(50574020); 中国博士后科学基金(2006039298); 辽宁省新材料重点实验室开放基金
摘    要:以含有定量纳米Al粉的Co基新型合金为涂层的原材料,在Cu-Cr合金表面利用Nd:YAG固体激光器诱导原位反应制备陶瓷相增强Co基复合涂层。采用金相显微镜、扫描电镜和显微硬度等分析技术,对所制备样品涂层的结构和形成机制进行了研究。结果表明:通过激光诱导原位反应,在铜合金表面制备出了组织细小、界面呈冶金结合的陶瓷相增强Co基涂层;涂层的显微硬度由基体表面显微硬度HV87提高到HV426;纳米Al粉的加入为激光诱导原位反应制备Co基涂层提供内部热源,弥补了铜合金基体因导热快而带来的能量损失,充分诱导涂层内的物质发生化学反应,有利于Co基复合涂层的形成;涂层中原位生成的陶瓷相直径小于2.0 μm,弥散分布在涂层中起到骨骼强化作用。 

关 键 词:脉冲激光  纳米Al粉  陶瓷相  Co基复合合金涂层
收稿时间:2007-09-14
修稿时间:2008-03-11

Particle reinforced Co-based composite alloy coating produced by laser inducing in-situ synthesis on the surface of copper alloy
CHEN Suiyuan,WANG Jianfang,LIU Changsheng,LIANG Jing. Particle reinforced Co-based composite alloy coating produced by laser inducing in-situ synthesis on the surface of copper alloy[J]. Acta Materiae Compositae Sinica, 2008, 25(4): 126-130
Authors:CHEN Suiyuan  WANG Jianfang  LIU Changsheng  LIANG Jing
Affiliation:(Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education,Northeastern University,Shenyang 110004,China)
Abstract:A new kind of Co-based alloy coating powder containing certain amount of nano-Al powder was designed. The ceramic phases in the coating were produced by YAG pulse laser inducing in-situ synthesis.  The microstructure morphology and the forming mechanism of the coating were studied by means of scan electronic microscope,optical micrograph analysis techniques and micro-hardness tester. By the pulse laser inducing in-situ synthesis,the interfaces of the thin coatings are metallurgically combined and  the ceramic particles are well dispersed. The micro-hardness of the Co-based composite alloy coating is promoted from HV87 to HV426. The added nano-Al supplies the interior heat fountain,which compensates for the energy loss  caused by the quick heat transmission of Cu-based alloy. The added nano-Al can fully induce the interior chemical reaction,which improves the composite coating forming easily. Ceramic particles are less than 2.0 μm in diameter and dispersed in the strengthened coating.
Keywords:pulsed laser; nano-Al; ceramic phase; Co-based composite alloy coating
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