| 水煤气有机硫转化脱除工艺技术的探讨与选择建议 |
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| 引用本文： | 杨清民,李金喜. 水煤气有机硫转化脱除工艺技术的探讨与选择建议[J]. 煤化工, 2012, 40(5): 55-58 |
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| 作者姓名： | 杨清民 李金喜 |
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| 作者单位： | 1. 山西焦煤集团有限责任公司,山西太原,030024
2. 山西焦化集团有限公司,山西 洪洞,041606 |
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| 摘 要： | 分析比较了目前水煤气(或半水煤气)中转化脱除有机硫的5种工艺流程和生产装置的运行特点,指出了COS和CS2加氢、水解转化过程中产生硫醚、硫醇的问题,提出按水煤气深加工(后工序)对总硫及煤气成分要求不同合理选择有机硫转化脱除工艺的建议。
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| 关 键 词： | 水煤气 有机硫 加氢转化 水解 工艺 建议 |
Study and Selection Suggestions of the Conversional Removal Technology of Organic Sulfur in Water Gas |
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| Yang Qingmin , Li Jinxi. Study and Selection Suggestions of the Conversional Removal Technology of Organic Sulfur in Water Gas[J]. Coal Chemical Industry, 2012, 40(5): 55-58 |
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| Authors: | Yang Qingmin Li Jinxi |
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| Affiliation: | 1.Shanxi Coking Coal Group Co.,Ltd.,Taiyuan Shanxi 030024,China; 2.Shanxi Coking Group Co.,Ltd.,Hongtong Shanxi 041606,China) |
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| Abstract: | Five current processes and the operational characteristics of their production units for conversional re- moval of organic sulfur from the water-gas （or semi-water gas） were analyzed and compared and the occurrence of thioether and mercaptan during the hydrogenation and hydrolysis conversion of COS and CS2 was pointed out. Suggestions as to how to select the right organic sulfur conversional removal process to meet the different total sulfur and gas composi- tion requirements in water-gas deep-processing （later process） was presented. |
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| Keywords: | water gas organic sulfur hydro-conversion hydrolysis process suggestions |
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