| 不可逆相转移法合成茶多酚砷配合物及光谱研究 |
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| 引用本文： | 周文富,何清松.不可逆相转移法合成茶多酚砷配合物及光谱研究[J].精细化工,2008,25(4):347-350. |
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| 作者姓名： | 周文富 何清松 |
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| 作者单位： | 三明学院,化学与生物工程系,福建,三明,365004;三明学院,化学与生物工程系,福建,三明,365004 |
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| 摘 要： | 采用不可逆相转移法,于水溶液中,在n(茶多酚)∶n(三氧化二砷)=10∶1,反应温度50~60℃,反应时间6h的条件下合成了标题化合物茶多酚砷。配合物的FTIR为:3417.16,1694.69,1619.55,1617.71,1508.95,1449.35,1351.99,1206.39,1037.54 cm-1。UV为:220 nm,3.700Abs;250 nm,1.100Abs;275 nm,1.800Abs。1HNMR,:δ1.180,2.840,5.409,6.058,6.490~7.123。白鼠急性口服毒性实验证实,合成的茶多酚砷为低毒有机物。
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| 关 键 词： | 茶多酚 砷配合物 结构表征 中药现代化技术 |
| 文章编号： | 1003-5214(2008)04-0347-04 |
| 修稿时间： | 2007年7月18日 |
Synthesis of Tea-polyphenol Arsenic Complex by Irreversible Phase Transfer and Its Characterizations |
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| ZHOU Wen-fu,HE Qing-song.Synthesis of Tea-polyphenol Arsenic Complex by Irreversible Phase Transfer and Its Characterizations[J].Fine Chemicals,2008,25(4):347-350. |
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| Authors: | ZHOU Wen-fu HE Qing-song |
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| Abstract: | In aqueous solution,by means of irreversible phase transfer,tea-polyphenol and AS2O3 in molar ratio 10∶1 reacted at 50～60 ℃ for 6 h to afford the title complex.The product was characterized by FTIR:ν=3 417.16,1 694.69,1 619.55,1 617.71,1 508.95,1 449.35,1 351.99,1 206.39,1 037.54 cm-1;UV:(220 nm,3.700Abs),(250 nm,1.100Abs),(275 nm,1.800Abs);and 1HNMR,δ:1.180,2.840,5.409,6.058,6.490～7.123.Rat acute oral toxicity show that,the synthesized tea-polyphenol arsenic complex proved to be an organic matter of low toxicity. |
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| Keywords: | tea-polyphenol arsenic complex structural characterization modernization technology of traditional Chinese medicines |
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