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Experimental and calculated liquid-liquid interfacial tension in demixing metal alloys
作者姓名:Walter  Hoyer  Ivan  Kaban
作者单位:Institute of Physics, Chemnitz University of Technology, D-09107 Chemnitz, Germany
基金项目:[This work is financially supported by the German Research Society (Deutsche Forschungsgemeinschafi) under grant H0 1688/8-2 in the frame of the priority research program 1120 “Phase transitions in multicomponent alloys” (“Phasenumwandlungen in merkomponentigen Schmelzen ”)]
摘    要:Liquid-liquid interracial tension in binary and temary Al-based monotectic systems has been determined experimentally with a tensiometric method in a wide temperature interval. The temperature dependence of the interfacial tension is well described by a power law function of the type σαβ - (1 - T/Tc)δ with the critical exponent δ= 1.3 and a critical temperature Tc. Theoretical models describing the liquid-liquid interface in monotectic alloys and their applicability for calculation of the interfacial tension and its temperature dependence in binary systems are considered.

关 键 词:不融和系统  铝基合金  液-液间张力  测量技术
收稿时间:2006-06-19

Experimental and calculated liquid-liquid interfacial tension in demixing metal alloys
Walter Hoyer Ivan Kaban.Experimental and calculated liquid-liquid interfacial tension in demixing metal alloys[J].Rare Metals,2006,25(5):452-456.
Authors:Walter Hoyer  Ivan Kaban
Affiliation:1. Department of Chemistry, Kurukshetra University, Kurukshetra 136119, Haryana, India;2. Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar 144 011, Punjab, India
Abstract:Liquid-liquid interfacial tension in binary and ternary Al-based monotectic systems has been determined experimentally with a tensiometric method in a wide temperature interval. The temperature dependence of the interfacial tension is well described by a power law function of the type σαβ~ (1 - T/Tc)δ with the critical exponent δ = 1.3 and a critical tem perature TC. Theoretical models describing the liquid-liquid interface in monotectic alloys and their applicability for calculation of the interfacial tension and its temperature dependence in binary systems are considered.
Keywords:immiscible systems  Al-based alloys  interfacial tension
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