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CSTR中三变量连续放热化学反应模型的非线性分析
引用本文:刘赵淼.CSTR中三变量连续放热化学反应模型的非线性分析[J].北京工业大学学报,1999,25(3):96-101.
作者姓名:刘赵淼
作者单位:北京工业大学机械工程与应用电子技术学院!北京,100022
摘    要:研究了修正的CSTR中具有两步连续放热反应的三变量化学模型的非线性动力学现象.建立了CSTR中具有两步连续放热反应的三变量化学模型的量纲一的数学模型.并进行了数值模拟分析.结果表明,本文所研究的化学模型,通过改变对热反馈的控制,可以得到丰富的非线性化学动力学现象,牛顿冷却时间τN和量纲一的活化能量ε对反应的进行具有一定的控制作用.当其它的参数和ε值确定时,在一定的范围内变化τN的值,可以使化学反应产生振荡和混沌现象.

关 键 词:非线性  化学模型  热反馈  化学振荡  化学混沌  CSTR

The Non-linear Analysis of the Chemical Reaction Models of Three-variable Consecutive Exothermal Reactions in CSTR
Liu Zhaomiao.The Non-linear Analysis of the Chemical Reaction Models of Three-variable Consecutive Exothermal Reactions in CSTR[J].Journal of Beijing Polytechnic University,1999,25(3):96-101.
Authors:Liu Zhaomiao
Abstract:This paper is concerned with the non-linear kinetic phenomenon of thethree-variable chemical models with two consecutive exothermal reactions in CSTR Thenon-dimensional mathematic model of the chemical model is established and analyzedqualitatively by numerical simulation. It is seen from the results of the numericalsimulation that the rich non-linear kinetic phemomenon can be obtained by changingthermal feedback, and the reactions are controlled by the change of the Newton coolingtime τN and non-dimensional active energy ε. Chemical oscillations and chemical chaoscan be obtained by changing τN in a certain sphere under the condition thatthe εand other parameters are determined.
Keywords:non-linear  chemical models  thermal feedback  chemical oscillations  chemical chaos  CSTR  
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