Partial acidulation of an ‘unground’ phosphate rock: I. Preparation and characteristics |
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Authors: | SSS Rajan |
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Affiliation: | (1) Ruakura Soil and Plant Research Station, Private Bag, Hamilton, New Zealand |
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Abstract: | Partially acidulated phosphate rocks were prepared from unground North Carolina phsophate rock and H3PO4 by (i) mixing phosphate rock with the requisite amount of H3PO4, (ii) mixing with a portion of the acid followed by adding the remaining acid during granulation and (iii) single-step acidulation and granulation. The degrees of acidulation were 20, 30, 40 and 50%. Only 20% and 30% acidulations were done by method (iii). The phosphate rock granulated readily on addition of H3PO4 either as in method (ii) or (iii) and the products did not need external drying before storage. The citric and water soluble P showed that from the viewpoint of acid-phosphate rock interaction all three methods of preparation were satisfactory. The granules were equally strong as or stronger than commercially available single or triple superphosphate samples tested. The percent degradation on abrasion was less than 4% compared to about 8% for superphosphate and 0.4% for triple superphosphate. A sand incubation study suggested an interaction in the partially acidulated phosphate rock between the monocalcium phosphate component and unreacted phosphate rock which initially increased the solubility of P. |
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Keywords: | granulation partially acidulated phosphate rocks phosphoric acid phosphate rock |
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