| (4S,5S)-4,5-双(对甲苯磺酸酯甲基)-2-(6-氯)正己基-1,3-二氧戊环的合成 |
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| 引用本文： | 邹贵祥,贾卫民,张遂之.(4S,5S)-4,5-双(对甲苯磺酸酯甲基)-2-(6-氯)正己基-1,3-二氧戊环的合成[J].化学试剂,1999(3). |
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| 作者姓名： | 邹贵祥 贾卫民 张遂之 |
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| 作者单位： | 中国科学院大连化学物理研究所 |
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| 摘 要： | 以光活性Ｌｇ－（＋）－酒石酸为原料合成了尚未见文献报道的含Ｃ２对称轴的（４Ｓ，５Ｓ）－４，５－双（对甲苯磺酸酯甲基）－２－（６－氯）正己基－１，３－二氧戊环。对它进行了元素分析、氢核磁共振谱、碳核磁共振谱表征。
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| 关 键 词： | 合成，手性，酒石酸，C_2对称轴 |
Synthesis of a new compound(4S,5S)4,5bis(tosylmethyl)2(6chloro)hexyl1,3dioxolane with C2 axis
of symmetry |
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| Zou Guixiang,Jia Weimin,Zhang Suizhi.Synthesis of a new compound(4S,5S)4,5bis(tosylmethyl)2(6chloro)hexyl1,3dioxolane with C2 axis
of symmetry[J].Chemical Reagents,1999(3). |
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| Authors: | Zou Guixiang Jia Weimin Zhang Suizhi |
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| Abstract: | novel compound
(4S,5S)4,5bis(tosylmethyl)2(6chloro)hexyl1,3dioxolane was synthesized from Lg( )tartaric acid.It
was characterized by elemental analysis,1CNMR spectra. |
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| Keywords: | synthesis chirality tartaric acid C2 axis of symmetry |
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