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环氧化天然橡胶共交联改性EPDM/NR共混物的性能
引用本文:陈福林,杨坤民,岑兰,周彦豪.环氧化天然橡胶共交联改性EPDM/NR共混物的性能[J].合成橡胶工业,2006,29(5):347-350.
作者姓名:陈福林  杨坤民  岑兰  周彦豪
作者单位:广东工业大学,材料与能源学院,广东,广州,510006
摘    要:将三元乙丙橡胶(EPDM)与环氧化天然橡胶(ENR)共交联改性后,再与天然橡胶(NR)共混,考察了ENR共交联改性EPDM/NR共混胶的硫化特性、硫化胶的物理机械性能、溶胀指数和耐热空气老化性能,并对该硫化胶进行了差示扫描量热分析。结果表明,EPDM经过ENR共交联改性后与NR共混,ENR共交联改性EPDM/NR共混胶的交联程度明显提高,各相达到了同步交联,硫化胶的综合性能得到了显著改善。

关 键 词:环氧化天然橡胶  三元乙丙橡胶  天然橡胶  共交联  共混  物理机械性能  耐老化性能
文章编号:1000-1255(2006)05-0347-04
收稿时间:2005-12-16
修稿时间:2005-12-162006-04-26

Properties of ethylene propylene diene monomer co-crosslinking modified with epoxy natural rubber/natural rubber blends
Chen Fulin,Yang Kunmin,Cen Lan,Zhou Yanhao.Properties of ethylene propylene diene monomer co-crosslinking modified with epoxy natural rubber/natural rubber blends[J].China Synthetic Rubber Industry,2006,29(5):347-350.
Authors:Chen Fulin  Yang Kunmin  Cen Lan  Zhou Yanhao
Affiliation:Faculty of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
Abstract:Natural rubber(NR) was blended with ethylene propylene diene monomer(EPDM) that was co-crosslinking modified with a small amount of epoxy natural rubber(ENR).The vulcanization characteristics,the mechanical properties,the swelling ratio in toluene,and the heat aging resistance of the blends were examined and the differential scanning calorimetry of the blending vulcanizates was conducted.The results showed that the polarity of EPDM increased,and its solubility to the fittings of the curing system increased after co-vulcanization with ENR.Co-vulcanization of the(EPDM) co-crosslinking modified with ENR/NR blending vulcanizates was improved to achieve synchronous crosslinking,and the mechanical properties of the EPDM co-crosslinking modified with ENR/NR blending vulcanizates improved greatly.
Keywords:epoxy natural rubber  ethylene propylene diene monomer  natural rubber  co-crosslinking  blend  mechanical property  aging resistance
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